Pr3+-doped YPO4 nanocrystal embedded into an optical fiber.

Optical fiber with YPO4:Pr3+ nanocrystals (NCs) is presented for the first time using the glass powder-NCs doping method. The method's advantage is separate preparation of NCs and glass to preserve luminescent and optical properties of NCs once they are incorporated into optical fiber. The YPO4:Pr3+ nanocrystals were synthesized by the co-precipitation and hydrothermal methods, optimized for size (< 100 nm), shape, Pr3+ ions concentration (0.2 mol%), and emission lifetime. The core glass was selected from the non-silica P2O5-containing system with refractive index (n = 1.788) close to the NCs (no = 1.657, ne = 1.838). Optical fiber was drawn by modified powder-in-tube method after pre-sintering of glass powder-YPO4:Pr3+ (wt 3%) mixture to form optical fiber preform. Luminescent properties of YPO4:Pr3+ and optical fiber showed their excellent agreement, including sharp Pr3+ emission at 600 nm (1D2-3H4) and 1D2 level lifetime (τ = 156 ± 5 µs) under 488 nm excitation. The distribution of the YPO4:Pr3+ NCs in optical fiber were analyzed by TEM-EDS in the core region (FIB-SEM-prepared). The successful usage of glass powder-NCs doping method was discussed in the aspect of promising properties of the first YPO4:Pr3+ doped optical fiber as a new way to develop active materials for lasing applications, among others.

Generation of infrared photon pairs by spontaneous four-wave mixing in a CS2-filled microstructured optical fiber.

We experimentally demonstrate frequency non-degenerate photon-pair generation via spontaneous four-wave mixing from a novel CS2-filled microstructured optical fiber. CS2 has high nonlinearity, narrow Raman lines, a broad transmission spectrum, and also has a large index contrast with the microstructured silica fiber. We can achieve phase matching over a large spectral range by tuning the pump wavelength, allowing the generation of idler photons in the infrared region, which is suitable for applications in quantum spectroscopy. Moreover, we demonstrate a coincidence-to-accidental ratio of larger than 90 and a pair generation efficiency of about [Formula: see text] per pump pulse, which shows the viability of this fiber-based platform as a photon-pair source for quantum technology applications.

Double-clad ytterbium-doped tapered fiber with circular birefringence as a gain medium for structured light.

Amplifying radially and azimuthally polarized beams is a significant challenge due to the instability of the complex beam shape and polarization in inhomogeneous environment. In this Letter, we demonstrated experimentally an efficient approach to directly amplify cylindrical-vector beams with axially symmetric polarization and doughnut-shaped intensity profile in a picosecond MOPA system based on a double-clad ytterbium-doped tapered fiber. To prevent polarization and beam shape distortion during amplification, for the first time to the best of our knowledge, we proposed using the spun architecture of the tapered fiber. In contrast to an isotropic fiber architecture, a spun configuration possessing nearly circular polarization eigenstates supports stable wavefront propagation. Applying this technique, we amplified the cylindrical-vector beam with 10 ps pulses up to 22 W of the average power at a central wavelength of 1030 nm and a repetition rate of 15 MHz, maintaining both mode and polarization stability.

Highly birefringent microstructured optical fiber for distributed hydrostatic pressure sensing with sub-bar resolution.

We demonstrate distributed optical fiber-based pressure measurements with sub-bar pressure resolution and 1 m spatial resolution over a ∼100 m distance using a phase-sensitive optical time-domain reflectometry technique. To do so, we have designed a novel highly birefringent microstructured optical fiber that features a high pressure to temperature sensitivity ratio, a high birefringence and a mode field diameter that is comparable to that of conventional step-index single mode fibers. Our experiments with two fibers fabricated according to the design confirm the high polarimetric pressure sensitivities (-62.4 rad×MPa-1×m-1 and -40.1 rad×MPa-1×m-1) and simultaneously low polarimetric temperature sensitivities (0.09 rad×K-1×m-1 and 0.2 rad×K-1×m-1), at a wavelength of 1550 nm. The fiber features a sufficiently uniform birefringence over its entire length (2.17×10-4 ± 7.65×10-6) and low propagation loss (∼3 dB/km), which allows envisaging pressure measurements along distances up to several kilometers.

Controlling Growth of Poly (Triethylene Glycol Acrylate-Co-Spiropyran Acrylate) Copolymer Liquid Films on a Hydrophilic Surface by Light and Temperature.

A quartz crystal microbalance with dissipation monitoring (QCM-D) was employed for in situ investigations of the effect of temperature and light on the conformational changes of a poly (triethylene glycol acrylate-co-spiropyran acrylate) (P (TEGA-co-SPA)) copolymer containing 12-14% of spiropyran at the silica-water interface. By monitoring shifts in resonance frequency and in acoustic dissipation as a function of temperature and illumination conditions, we investigated the evolution of viscoelastic properties of the P (TEGA-co-SPA)-rich wetting layer growing on the sensor, from which we deduced the characteristic coil-to-globule transition temperature, corresponding to the lower critical solution temperature (LCST) of the PTEGA part. We show that the coil-to-globule transition of the adsorbed copolymer being exposed to visible or UV light shifts to lower LCST as compared to the bulk solution: the transition temperature determined acoustically on the surface is 4 to 8 K lower than the cloud point temperature reported by UV/VIS spectroscopy in aqueous solution. We attribute our findings to non-equilibrium effects caused by confinement of the copolymer chains on the surface. Thermal stimuli and light can be used to manipulate the film formation process and the film's conformational state, which affects its subsequent response behavior.

Pre-compensation of thermally induced refractive index changes in a depressed core fully aperiodic large-pitch fiber for high average power operation.

To prevent the thermally induced spatial beam degradation occurring in high-power fiber lasers and amplifiers, index-depressed core "fully aperiodic large-pitch fibers" (FA-LPFs) have been designed and fabricated. In contrast to previous experimental works performed on FA-LPFs, in which the active core and the surrounding cladding material are quasi-index-matched, the core refractive index is in slight depression compared to the surrounding material (Δn≈-3×10-5). Thus, the index-depressed fiber core tends first to behave as an anti-guide, preventing light from being properly guided into it. However, by increasing the absorbed pump power, the thermal load induces a parabolic refractive index change sufficient to compensate for the -3×10-5 index depression in the core, enabling a robust single-mode amplification at high average power. As a proof of concept, using a 110 µm depressed core FA-LPF, M2 values of 1.3 were demonstrated in amplifier configuration from 60 W to a maximal value of 170 W of emitted average power only limited by the available pump power.

Negative curvature hollow core fiber sensor for the measurement of strain and temperature.

Three different types of strain and temperature sensors based on negative curvature hollow core fiber (NCHCF) are proposed. Each sensor is produced by splicing a small section of the NCHCF between two sections of single mode fiber. Different types of interferometers are obtained simply by changing the splicing conditions. The first sensor consists on a single Fabry-Perot interferometer (FPI). The remaining two configurations are attained with the same sensing structure, depending on its position in relation to the interrogation setup. Thus, a double FPI or a hybrid sensor, the latter being composed by an FPI and a Michelson interferometer, are formed. The inline sensors are of submillimeter size, thus enabling nearly punctual measurements.

2 MW peak power generation in fluorine co-doped Yb fiber prepared by powder-sinter technology.

We report on the first, to the best of our knowledge, implementation of a fluorine co-doped large-mode-area REPUSIL fiber for high peak power amplification in an ultrashort-pulse master oscillator power amplifier. The core material of the investigated step-index fiber with high Yb-doping level, 52 µm core and high core-to-clad ratio of 1:4.2 was fabricated by means of the REPUSIL powder-sinter technology. The core numerical aperture was adjusted by fluorine codoping to 0.088. For achieving high beam quality and for ensuring a monolithic seed path, the LMA fiber is locally tapered. We demonstrate an Yb fiber amplifier with near-diffraction-limited beam quality of M2=1.3, which remains constant up to a peak power of 2 MW. This is a record for a tapered single core fiber.

Sodium Ion Conductivity in Superionic IL-Impregnated Metal-Organic Frameworks: Enhancing Stability Through Structural Disorder.

Metal-organic frameworks (MOFs) are intriguing host materials in composite electrolytes due to their ability for tailoring host-guest interactions by chemical tuning of the MOF backbone. Here, we introduce particularly high sodium ion conductivity into the zeolitic imidazolate framework ZIF-8 by impregnation with the sodium-salt-containing ionic liquid (IL) (Na0.1EMIM0.9)TFSI. We demonstrate an ionic conductivity exceeding 2 × 10-4 S · cm-1 at room temperature, with an activation energy as low as 0.26 eV, i.e., the highest reported performance for room temperature Na+-related ion conduction in MOF-based composite electrolytes to date. Partial amorphization of the ZIF-backbone by ball-milling results in significant enhancement of the composite stability towards exposure to ambient conditions, up to 20 days. While the introduction of network disorder decelerates IL exudation and interactions with ambient contaminants, the ion conductivity is only marginally affected, decreasing with decreasing crystallinity but still maintaining superionic behavior. This highlights the general importance of 3D networks of interconnected pores for efficient ion conduction in MOF/IL blends, whereas pore symmetry is a less stringent condition.

Widely tunable Q-switched dual-wavelength synchronous-pulsed Tm-doped fiber laser emitting in the 2 µm region.

We demonstrate a widely tunable Q-switched dual-wavelength fiber laser emitting synchronized pulses in the 2 µm spectral range. Owing to the use of a Tm-doped rod-type fully aperiodic large pitch fiber, together with an acousto-optic modulator and two volume Bragg gratings (VBGs), the wavelength separation was shown to be continuously tunable from 1 to 120 nm (∼0.1-10 THz). A peak power higher than 8 kW was demonstrated over the whole tuning range for a repetition rate (RR) of 1 KHz and a 26 ns pulse duration. The RR was modulated from 1 to 30 kHz, and the laser pulse duration measured between 23 ns and 130 ns, depending on the RR and the wavelength separation.

Biomimetic light dilution using side-emitting optical fiber for enhancing the productivity of microalgae reactors.

Photoautotrophic microbes present vast opportunities for sustainable lipid production, CO2 storage and green chemistry, for example, using microalgae beds to generate biofuels. A major challenge of microalgae cultivation and other photochemical reactors is the efficiency of light delivery. In order to break even on large scale, dedicated photon management will be required across all levels of reactor hierarchy - from the harvesting of light and its efficient injection and distribution inside of the reactor to the design of optical antenna and pathways of energy transfer on molecular scale. Here, we discuss a biomimetic approach for light dilution which enables homogeneous illumination of large reactor volumes with high optical density. We show that the immersion of side-emitting optical fiber within the reactor can enhance the fraction of illuminated volume by more than two orders of magnitude already at cell densities as low as ~5 104 ml-1. Using the green algae Haematococcus pluvialis as a model system, we demonstrate an increase in the rate of reproduction by up to 93%. Beyond micoralgae, the versatile properties of side-emitting fiber enable the injection and dilution of light with tailored spectral and temporal characteristics into virtually any reactor containment.

Boson peak, heterogeneity and intermediate-range order in binary SiO2-Al2O3 glasses.

In binary aluminosilicate liquids and glasses, heterogeneity on intermediate length scale is a crucial factor for optical fiber performance, determining the lower limit of optical attenuation and Rayleigh scattering, but also clustering and precipitation of optically active dopants, for example, in the fabrication of high-power laser gain media. Here, we consider the low-frequency vibrational modes of such materials for assessing structural heterogeneity on molecular scale. We determine the vibrational density of states VDoS g(ω) using low-temperature heat capacity data. From correlation with low-frequency Raman spectroscopy, we obtain the Raman coupling coefficient. Both experiments allow for the extraction of the average dynamic correlation length as a function of alumina content. We find that this value decreases from about 3.9 nm to 3.3 nm when mildly increasing the alumina content from zero (vitreous silica) to 7 mol%. At the same time, the average inter-particle distance increases slightly due to the presence of oxygen tricluster species. In accordance with Loewensteinian dynamics, this proves that mild alumina doping increases structural homogeneity on molecular scale.

Fast, Label-Free Tracking of Single Viruses and Weakly Scattering Nanoparticles in a Nanofluidic Optical Fiber.

High-speed tracking of single particles is a gateway to understanding physical, chemical, and biological processes at the nanoscale. It is also a major experimental challenge, particularly for small, nanometer-scale particles. Although methods such as confocal or fluorescence microscopy offer both high spatial resolution and high signal-to-background ratios, the fluorescence emission lifetime limits the measurement speed, while photobleaching and thermal diffusion limit the duration of measurements. Here we present a tracking method based on elastic light scattering that enables long-duration measurements of nanoparticle dynamics at rates of thousands of frames per second. We contain the particles within a single-mode silica fiber having a subwavelength, nanofluidic channel and illuminate them using the fiber's strongly confined optical mode. The diffusing particles in this cylindrical geometry are continuously illuminated inside the collection focal plane. We show that the method can track unlabeled dielectric particles as small as 20 nm as well as individual cowpea chlorotic mottle virus (CCMV) virions-26 nm in size and 4.6 megadaltons in mass-at rates of over 3 kHz for durations of tens of seconds. Our setup is easily incorporated into common optical microscopes and extends their detection range to nanometer-scale particles and macromolecules. The ease-of-use and performance of this technique support its potential for widespread applications in medical diagnostics and micro total analysis systems.

Fabry-Perot cavity based on silica tube for strain sensing at high temperatures.

In this work, a Fabry-Perot cavity based on a new silica tube design is proposed. The tube presents a cladding with a thickness of ~14 µm and a hollow core. The presence of four small rods, of ~20 µm diameter each, placed in diametrically opposite positions ensure the mechanical stability of the tube. The cavity, formed by splicing a section of the silica tube between two sections of single mode fiber, is characterized in strain and temperature (from room temperature to 900 °C). When the sensor is exposed to high temperatures, there is a change in the response to strain. The influence of the thermal annealing is investigated in order to improve the sensing head performance.

Origins of modal loss of antiresonant hollow-core optical fibers in the ultraviolet.

Recently, a novel antiresonant hollow core fiber was introduced having promising UV guiding properties. Accompanying simulations predicted ten times lower loss than observed experimentally. Increasing loss is observed in many antiresonant fibers with the origin being unknown. Here, two possible reasons for the enhanced loss are discussed: strand thickness variation and surface roughness scattering. Our analysis shows that the attenuation is sensitive to thickness variations of the strands surrounding the hollow-core which strongly increase loss at short wavelengths. The contribution of surface roughness stays below the dB/km level and can be neglected. Thus, preventing structural irregularities by improved fabrication approaches is essential for decreasing loss.

Optical breathing of nano-porous antireflective coatings through adsorption and desorption of water.

We report on the direct consequences of reversible water adsorption on the optical performance of silica-based nanoporous antireflective (AR) coatings as they are applied on glass in photovoltaic and solar thermal energy conversion systems. In situ UV-VIS transmission spectroscopy and path length measurements through high-resolution interferometric microscopy were conducted on model films during exposure to different levels of humidity and temperature. We show that water adsorption in the pores of the film results in a notable increase of the effective refractive index of the coating. As a consequence, the AR effect is strongly reduced. The temperature regime in which the major part of the water can be driven-out rapidly lies in the range of 55°C and 135°C. Such thermal desorption was found to increase the overall transmission of a coated glass by ~ 1%-point. As the activation energy of isothermal desorption, we find a value of about 18 kJ/mol. Within the experimental range of our data, the sorption and desorption process is fully reversible, resulting in optical breathing of the film. Nanoporous AR films with closed pore structure or high hydrophobicity may be of advantage for maintaining AR performance under air exposure.

Double antiresonant hollow core fiber--guidance in the deep ultraviolet by modified tunneling leaky modes.

Guiding light inside the hollow cores of microstructured optical fibers is a major research field within fiber optics. However, most of current fibers reveal limited spectral operation ranges between the mid-visible and the infrared and rely on complicated microstructures. Here we report on a new type of hollow-core fiber, showing for the first time distinct transmission windows between the deep ultraviolet and the near infrared. The fiber, guiding in a single mode, operates by the central core mode being anti-resonant to adjacent modes, leading to a novel modified tunneling leaky mode. The fiber design is straightforward to implement and reveals beneficial features such as preselecting the lowest loss mode (Gaussian-like or donut-shaped mode). Fibers with such a unique combination of attributes allow accessing the extremely important deep-UV range with Gaussian-like mode quality and may pave the way for new discoveries in biophotonics, multispectral spectroscopy, photo-initiated chemistry or ultrashort pulse delivery.

Acoustic second harmonic generation from rough surfaces under shear excitation in liquids.

Emission of compressional acoustic waves at the second harmonic frequency (second harmonic generation, SHG) is possible from rough surfaces undergoing oscillatory shear in liquids. This nonlinear response is a consequence of the inertial term in the Navier-Stokes equation. On a corrugated surface, the streamlines of the sheared liquid are not strictly parallel to the surface, leading to variation of pressure along the streamlines and a concomitant Bernoulli pressure. Being quadratic in speed, the Bernoulli pressure contains a static term and a term at the second harmonic frequency, 2omega. Pressure fluctuations at 2omega generate compressional waves.

Roughness-induced acoustic second-harmonic generation during electrochemical metal deposition on the quartz-crystal microbalance.

This paper reports on the relation between the surface roughness and emission of compressional waves from the surface of an electrochemical quartz-crystal microbalance. The detection of the compressional waves took place with an ultrasonic microphone and the quartz crystal itself. As a model process, the electrochemical deposition of copper from an acidic copper sulfate solution has been chosen. For this system, the roughness of the layer can be tuned via the current density. Roughness may be a source of the longitudinal waves at twice the frequency of the exciting shear wave (acoustic second-harmonic generation, ASHG) if the flow profile above the quartz-crystal surface is not entirely laminar. Slight deviations from the laminar flow can be reached at high amplitudes of oscillation. Comparing the ASHG efficiency of a rough and smooth surface, we find that the rough surface is more efficient in generating second-harmonic waves. This suggests that ASHG can be used to obtain a roughness parameter independent from the resonance frequency or bandwidth (damping) of a quartz-crystal resonator. Such an independent determination of roughness should be very interesting in practical applications.